Zero Order Reaction
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Q. The initial rate of zero order reaction of the gaseous reaction A(g) → 2B(g) is 10−2 M/min. If the initial concentration of A is 0.1 M, what would be the concentration of B after 60 sec?
- 0.01 M
- 0.09 M
- 0.02 M
- 0.002 M
Q. The units of rate constant and rate of reaction are identical for
- first order reaction
- zero order reaction
- second order reaction
- pseudo first order reaction
Q. H2O2→H2O+O2
The rate constant of this reaction is 2×10−2 min−1 (at certain temperature) and reaction is started with 0.5 M concentration of H2O2, after 23.03 min the reaction was suddenly stopped by lowering the temperature and remaining H2O2 was completely reacted with NaOCl, if number of moles of O2 produced in second reaction is 1x. Find x.
(Given : NaOCl+H2O2→O2+NaCl+H2Olog1.5=0.2)
The rate constant of this reaction is 2×10−2 min−1 (at certain temperature) and reaction is started with 0.5 M concentration of H2O2, after 23.03 min the reaction was suddenly stopped by lowering the temperature and remaining H2O2 was completely reacted with NaOCl, if number of moles of O2 produced in second reaction is 1x. Find x.
(Given : NaOCl+H2O2→O2+NaCl+H2Olog1.5=0.2)
Q. Consider the zero order reaction
R→P
Starting with 4 moles of R in a one litre container, after half an hour only 1 mole of R is left unreacted. The value of k for the reaction is:
R→P
Starting with 4 moles of R in a one litre container, after half an hour only 1 mole of R is left unreacted. The value of k for the reaction is:
- 1molL−1min−1
- 0.4molL−1min−1
- 0.1molL−1min−1
- 0.3molL−1min−1
Q. Half-life period of a zero order reaction is
- Inversely proportional to square of initial concentration of reactants.
- Proportional to initial concentration of reactants
- Independent of initial concentration of reactants
- Inversely proportional to initial concentration of reactants
Q. The time required for 100% completion of a zero order reaction is (a is the initial concentration and k is the rate constant)
- 2Ka
- a2K
- aK
- aK
Q.
Match the following
Order of reaction Half-life period
1)1st order reaction a) (ka0)−1
2) Second order reaction b) 0.693k
3) Zero order reaction c) a02k
- 1-a , 2-b, 3-c
- 1-b, 2-a, 3-c
- 1-b, 2-c, 3-a
- 1-c, 2-b, 3-a
Q. Sita has to select one reaction out of zero order, first order, second order, and a third order reaction such that, the rate of reaction is constant throughout the reaction. Which one should she select?
- Zero order reaction
- first order reaction
- Second order reaction
- third order reaction
Q. How does the graph (concentration vs time) of a zero order reaction look like?
Q. If the rate of a reaction is equal to the rate constant, the order of the reaction is:
- 1
- 3
- 0
- 2