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Question

A 1.00L vessel containing 1.00 g H2 gas at 270C is connected to a 2.00 L vessel containing 88.0g CO2 gas, at also 270C. When the gases are completely mixed, total pressure is:

A
20.5 atm
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B
4.1 atm
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C
16.4 atm
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D
730.7 atm
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Solution

The correct option is A 20.5 atm
PTotal=PA+PB T=27+273=300K; nH2=12=0.5 moles
PA=PH2=(nH2)RTV
=0.5×0.082×3003
=4.1atm
PB=PCO2=nCO2RTV nCO2=8844=2 moles
=2×0.082×3003
=16.4atm
PTotal=4.1+16.4=20.5atm

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