A 2.24L cylinder of oxygen at 1atm and 273K is found to develop a leakage. When the leakage was plugged the pressure dropped to 570mm of Hg. The number of moles of gas that escaped will be:
A
0.025
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B
0.050
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C
0.075
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D
0.09
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Solution
The correct option is D0.025
Original pressure, (Pi)=1 atm=760 mmHg
Final pressure, (Pf)=570 mmHg
∴ Drop in pressure, (P)=Pi−Pf=(760−570) mmHg=190 mmHg=190760 atm
Volume, (V)=2.24L
R=0.0821 L atm K−1mol−1
Temperature, (T)=273K
According to ideal gas equation,
PV=nRT
⇒n=PVRT
⇒n=(190760)×2.240.0821×273=0.02498=0.025 moles
Hence the number of moles of gas that escaped will be 0.025 moles.