A 25.0mL sample of 0.10MHCl is titrated with 0.10MNaOH. What is the pH of the solution at the points where 24.9 and 25.1mL of NaOH have been added?
A
3.70,10.70
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B
3.30,10.30
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C
3.70,10.30
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D
3.0,11.0
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Solution
The correct option is A3.70,10.70 Molarity is 0.1M so its each ml contains 10−4 moles of ions. At 24.9 ml, hydrogen ion is excess so pH is 3.7 and at 25.1 ml, hydroxide ion are in excess so pH is 10.7