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Question

A 25.0 mL sample of 0.10 M HCl is titrated with 0.10 M NaOH. What is the pH of the solution at the points where 24.9 and 25.1 mL of NaOH have been added?

A
3.70, 10.70
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B
3.30, 10.30
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C
3.70, 10.30
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D
3.0, 11.0
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Solution

The correct option is A 3.70, 10.70
Molarity is 0.1M so its each ml contains 104 moles of ions. At 24.9 ml, hydrogen ion is excess so pH is 3.7 and at 25.1 ml, hydroxide ion are in excess so pH is 10.7

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