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Question


A 3o alcohol as shown can be obtained by the reaction of ketone (diisopropyl ketone) and__________.
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A
isopropyl magnesium bromide
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B
isopropyl lithium
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C
diisopropyl cadmium
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D
diisopropyl zinc
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Solution

The correct option is C isopropyl lithium
R.. in RLi is more nucleophilic than in RMgX, or R2Cd or R2Zn and therefore, is sufficiently reactive to overcome the steric hindrance.
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