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Question

A 6.50 molal solution of KOH(aq) has a density of 1.89 g cm3. The molarity of the solution is mol dm3. (Round off to the nearest integer).
[Atomic masses:K=39.0 u, O=16.0 u, H=1.0 u]

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Solution

By using the relation,
m=1000×M(1000×d)M×MsoluteWhere, m=molality of the solution=6.50 mM=molarity of the solutiond=density=1.89 g cm3Msolute=Molar mass of solute=39+16+1=56 uSubstituting the values, we get6.5=1000×M1890M×5612285364M=1000M1364M=12285M=9 mol dm3

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