By using the relation,
m=1000×M(1000×d)−M×MsoluteWhere, m=molality of the solution=6.50 mM=molarity of the solutiond=density=1.89 g cm−3Msolute=Molar mass of solute=39+16+1=56 uSubstituting the values, we get6.5=1000×M1890−M×56⇒12285−364M=1000M⇒1364M=12285⇒M=9 mol dm−3