(A), (B), (C), (D), (E) and (F) base on the reactions are
A : ZnS B : H2S C : ZnSO4 D : PbS E : Zn(OH)2 F : Na2ZnO2 or Na2[Zn(OH)4]
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Solution
The compound A is ZnS The compound B is H2S The compound C is ZnSO4 The compound D is PbS The compound E is Zn(OH)2 The compound F is Na2ZnO2 or Na2[Zn(OH)4] ZnS reacts with dil sulphuric acid to form hydrogen sulphide gas and zinc sulphate. ZnS+H2SO4→ZnSO4+H2S Hydrogen sulphide gas reacts with lead acetate to form black ppt of lead sulphide/ Pb(CH3COO)2+H2S→PbS↓(black)+2CH3COOH Znc sulphate reacts with NaOH solution to form white ppt of sodium hydroxide which is soluble in excess NaOH to form ZnSO4+2NaOH→Zn(OH)2↓+NaSO4 Zn(OH)2+2NaOH→|undersetsodiumzincateNa2ZnO2+2H2O sodium zincate. Sodium zincate reacts with hydrogen sulphide gas to form zinc sulphide. Na2ZnO2+H2S→ZnS+2NaOH Zinc sulphate reacts with ammonium hydroxide in presence of ammonium chloride and hydrogen sulphide to form zinc sulphide. ZnSO4+2NH4OHheat−−→(NH4)2SO4+Zn(OH)2 Zn(OH)2+H2S→ZnS+2H2O