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Question


(A), (B), (C), (D), (E) and (F) base on the reactions are

A : ZnS
B : H2S
C : ZnSO4
D : PbS
E : Zn(OH)2
F : Na2ZnO2 or Na2[Zn(OH)4]

If the given statement is true enter 1, else enter 0.

203103_303101377ff1496c84e5c25f7f163412.png

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Solution

The compound A is ZnS
The compound B is H2S
The compound C is ZnSO4
The compound D is PbS
The compound E is Zn(OH)2
The compound F is Na2ZnO2 or Na2[Zn(OH)4]
ZnS reacts with dil sulphuric acid to form hydrogen sulphide gas and zinc sulphate.
ZnS+H2SO4ZnSO4+H2S
Hydrogen sulphide gas reacts with lead acetate to form black ppt of lead sulphide/
Pb(CH3COO)2+H2SPbS(black)+2CH3COOH
Znc sulphate reacts with NaOH solution to form white ppt of sodium hydroxide which is soluble in excess NaOH to form
ZnSO4+2NaOHZn(OH)2+NaSO4
Zn(OH)2+2NaOH|undersetsodiumzincateNa2ZnO2+2H2O
sodium zincate.
Sodium zincate reacts with hydrogen sulphide gas to form zinc sulphide.
Na2ZnO2+H2SZnS+2NaOH
Zinc sulphate reacts with ammonium hydroxide in presence of ammonium chloride and hydrogen sulphide to form zinc sulphide.
ZnSO4+2NH4OHheat(NH4)2SO4+Zn(OH)2
Zn(OH)2+H2SZnS+2H2O

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