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Question

A beam of ultraviolet radiation having wavelength between 100nm and 200nm is incident on a sample of atomic hydrogen gas. Assuming that the atoms are in ground state, which wavelengths will have low intensity in the transmitted beam?

A
104nm
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B
103nm
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C
105nm
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D
100nm
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Solution

The correct option is A 103nm
Energy corresponding to wavelength 100nm, 1242eV100=12.42eV
Energy corresponding to wavelength 200nm, 1242eV200=6.21eV
Energy required from ground state to first excited stage:
E2E1=13.63.4=10.2eV
Energy required from ground state to second excited stage:
E3E1=13.613.61.5=12.1eV
Energy required from ground state to third excited stage:
E3E1=13.60.85=12.75eV
At 10.2 eV,
Wavelength1=124210.2=122nm
At 12.1 eV,
Wavelength2=124212.1=103nm




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