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Question

A black colored (insoluble in H2O) solid A does not dissolve in HNO3. Aqua regia can dissolve A forming B. B gives yellow precipitate C with NaOH. B also gives an orange ppt. D with KI. D dissolves in excess of KI forming E. E gives brown ppt. with NH+4 salt in presence of NaOH. A is precipitated if H2S gas is passed into the solution of B in dil.HCl.

The compound C is :

A
HgCl2
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B
PbCl2
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C
HgO
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D
PbO
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Solution

The correct option is C HgO
Reaction:
HgCl2+2NaOHHgO+2NaCl+H2O
B C
354529_274351_ans.png

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