False
example 1 Just throw a ball vertically upwards in the air. It is constantly accelerating (decelerating, in this case) with 'g' in the downward direction. And at the topmost point, when it's velocity goes down to zero for an instant, it's still accelerating (with same 'g' in the downward direction).
example 2 Consider a body moving along positive X direction with a velocity of 10 m/s.
It has a constant acceleration of 2 m/s^2 in the negative X direction (Essentially retardation).
At exactly 5 seconds, the velocity of the particle will be zero, but it'll still have a constant acceleration of 2 m/s^2 in the negative X direction.