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Question

A bottle is heated with its mouth open from 15oC to 100oC. What fraction of air originally contained in the vessel is expelled?

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Solution

Volume & pressure will remain same as the bottle volume is fixed at constant pressure.

n.T=constant

niTi=nfTf

ninf=TfTi=378288

% Fractional removed =(1nfni)×100

=(1TiTf)×100=(1288373)×100=22.8%

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