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Question

A box of 1-litre capacity is divided into two equal compartments by a thin partition which is filled with 6g of H2 and 16 g CH4 respectively.The pressure in each compartment is recorded as P atm. The total pressure when partition is removed will be:

A
P
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B
2P
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C
P/2
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D
P/4
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Solution

The correct option is C P
Number of moles, nH2=6/2=3
and nCH4=16/16=1

PH2=33+1×P=34P
PCH4=13+1×P=P/4
ptotal=PH2+PCH4=34P+p4=P

Hence, option A is correct.

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