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Question

(a) Calculate ΔrG0 for the reaction Mg(s)+Cu2+(aq)Mg2+(aq)+Cu(s).
Given: E0cell=2.71V,1F=96500Cmol1
(b) Name the type of cell that was used in Apollo space program for providing electrical power.

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Solution

(a) For the cell reaction,

Mg(s)+Cu2+(aq)Mg2+(aq)+Cu(s); Eocell=+271V

The change in the standard Gibbs free energy is given as:

ΔrGo=nFEocell=2×96500×2.71=523030 Jmol1

b) The fuel cell which uses the reaction of hydrogen with oxygen to form water was used in Apollo space programme for providing electrical power.


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