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Question

A calorimeter of mass 50 g and specific heat capacity 0.42J.g-1.C-1contains some mass of water at 20C. A metal piece of mass 20 g at 100Cis dropped into the calorimeter. After stirring, the final temperature of the mixture is found to be 22C.Find the mass of water used in calorimeter.

(Take, specific heat capacity of metal piece = 0.3J.g-1.C-1and specific heat capacity of water = 0.42J.g-1.C-1)


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Solution

Step 1: Given data

Mass of calorimeter m=50g

Mass of the metal piece m'=20g

Specific heat capacity of the calorimeter c=0.42J.g-1.C-1

Highest temperature T'=100C

Final temperature T=22C

Lowest temperature T''=20C

Specific heat capacity of the metal piece c'=0.3J.g-1.C-1

Specific heat capacity of water c''=0.42J.g-1.C-1

Step 2: Finding heat lost

Heatlostbythemetalpiece=m'c'T'-TQ'=20g×0.3J.g-1.C-1×100C-22CQ'=468J

Step 3: Finding heat gained by the water

Heatgainedbywater=m''c''T-T''Q=m''×0.42J.g-1.C-1×22C-2CQ=8.4m''J

Step 4: Finding heat gained by the calorimeter

Heatgainedbycalorimeter=mcT-T''Q''=50g×0.42J.g-1.C-1×22C-20CQ''=42J

Step 5: Finding the mass of the water

Heatlost=Heatthegained468J=8.4m''J+42J426=8.4m''m''=50.71g

Thus the mass of the water is 50.71 g.


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