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Question

A carbon compound on analysis gives the following percentage composition. Carbon 14.5 , hydrogen 1.8 chlorine 64.6 , oxygen 19.24 . The empirical formula of the compound is:

A
C2H3Cl3O2
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B
C2HCl3O4
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C
C2H2Cl3O3
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D
C2H4Cl3O2
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Solution

The correct option is A C2H3Cl3O2
Percentage compostion of the elements present in the compound,
C:H:Cl:O=14.5:1.8:64.46:19.24

Dividing by molar mass we get the mole ratio as,
C:H:Cl:O=1.21:1.8:1.81:1.2

Dividing by the smallest number and converting the same to whole numbers, we get the simplest whole number ratio.
C:H:Cl:O=2:3:3:2

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