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Question

A certain dye absorbs 4000˚Aand fluoresces at 5000˚A these being wavelength of maximum absorption that under given conditions 40 of the absorbed energy is emitted. Calculate the ratio of the number of quanta emitted to the number absorbed.

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Solution

Energy of light absorbed in an photon =hc/λabsorbed
Let n1 photons are absorbed
Total energy absorbed =n1hc/λabsorbed
Now E of light re-emitted out in one photon =hc/λemitted
Let n2 photons are re-emitted then
Total energy re-emitted out =n2hc/λemitted
Eabsorbed×40/100=Ereemittedout
hc/λabsorbed×n1×40/100=n2×hcλemitted
n2/n1=40/100×λemittedλabsorbed
=40/100×5000/4000
n2/n1=0.5

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