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Question

A certain mixed oxide of iron contains 2.5 g of oxygen for every 7 g of iron. If it is regarded as a mixture of FeO and Fe2O3 in the weight ratio a:b, what is a:b?
(atomic weight of iron = 56)

A
9:10
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B
9:20
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C
14:5
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D
1:1
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Solution

The correct option is A 9:10
Consider x mol of FeO and y mol of Fe2O3 to be present.

FeOFe+OxxxFe2O32Fe+3Oy2y3y

Given: weight ratio, O:Fe=2.5:7
Therefore,
(x+3y)16(x+2y)56=2.57
x+3yx+2y=2.57×5616=2.52
Solving this, we get xy=21
wt. ratio,FeOFe2O3=21×72160=910

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