A certain mixed oxide of iron contains 2.5g of oxygen for every 7g of iron. If it is regarded as a mixture of FeO and Fe2O3 in the weight ratio a:b, what is a:b? (atomic weight of iron = 56)
A
9:10
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B
9:20
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C
14:5
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D
1:1
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Solution
The correct option is A9:10 Consider x mol of FeO and y mol of Fe2O3 to be present.
FeO→Fe+OxxxFe2O3→2Fe+3Oy2y3y
Given: weight ratio, O:Fe=2.5:7 Therefore, (x+3y)16(x+2y)56=2.57 ⇒x+3yx+2y=2.57×5616=2.52 Solving this, we get xy=21 ⇒wt. ratio,FeOFe2O3=21×72160=910