A certain reaction occurs in the following steps-i Clg-O3g- ClOg-O2gii ClOg-Og- Clg-O2g-What is the molecularity of each of the elementary steps-

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Molecularity of Reaction

A certain rea...

Question

A certain reaction occurs in the following steps.
(i) $C l_{(g)} + O_{3 (g)} \to C l O_{(g)} + O_{2 (g)}$
(ii) $C l O_{(g)} + O_{(g)} \to C l_{(g)} + O_{2 (g)}$ .
What is the molecularity of each of the elementary steps?

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C l_{(g)} + O_{3 (g)} \to C l O_{(g)} + O_{2 (g)}

C l O_{(g)} + O_{(g)} \to C l_{(g)} + O_{2 (g)}

O_{3}

O_{3} (g) + C l (g) ⟶ O_{2} (g) + C l O (g);

k_{1} = 5.2 \times 10^{9} L {m o l}^{- 1} {s e c}^{- 1}

C l O (g) + O (g) ⟶ C l (g) + O_{2} (g);

k_{2} = 2.6 \times 10^{10} L {m o l}^{- 1} {s e c}^{- 1}

O_{3} (g) + O (g) ⟶ 2 O_{2} (g)

N O_{(g)} + O_{3 (g)} ⟶ N O_{3 (g)} + O_{(g)}

H_{2} I_{(g)} + I_{(g)} ⟶ 2 H I_{(g)}

C l_{(g)} + C l_{(g)} + N_{2 (g)} ⟶ C l_{2 (g)} + N_{2 (g)}

O_{3} (g) ⇌ O_{2} (g) + O (g)

O (g) + O_{3} (g) \to 2 O_{2}

S t e p 1 : N_{2} O_{(g)} \to N_{2 (g)} + O_{(g)}

S t e p 2 : N_{2} O_{(g)} + O_{(g)} \to N_{2 (g)} + O_{2 (g)}

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