The standard form of the equation of a circle is
(x−a)2+(y−b)2=r2
where (a,b) are the coords of the centre and r, the radius.
x2+y2=16 is in this form
with a=b=0 and r=4
hence this circle has centre at the origin (0,0) and radius 4
The intercepts will therefore be (±4,0) and (0,±4).