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Question

(a) Classify following oxides as neutral, acidic, basic or amphoteric:

CO,B2O3,SiO2,CO2,Al2O3,PbO2,Tl2O3

(b)Write suitable chemical equations to show their nature.

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Solution

(1) CO = Neutral

(2) B2O3 = Acidic

Being acidic, it reacts with bases to form salts. It reacts with NaOH to form sodium metaborate.

B2O3+2NaOH2NaBO2+H2O

(3) SiO2 = Acidic

Being acidic, it reacts with bases to form salts. It reacts with NaOH to form sodium silicate.

SiO2+2NaOH2NA2Sio3+H2O

(4) CO2 = Acidic Being acidic, it reacts with bases to form salts. It reacts with NaOH to form sodium carbonate.

CO2+2NaOHNa2CO3+H2O

(5) Al2O3 = Amphoteric Amphoteric substances react with both acids and bases. Al2O3 reacts with both NaOH and H2SO4.

Al2O3+2NaOHNaAlO2 + H2O

Al2O3+3H2SO4Al2(SO4)3 + 3H2O

(6) PbO2 = Amphoteric Amphoteric substances react with both acids and bases. PbO2 reacts with both NaOH and H2SO4.

PbO2+2NaOHNa2PbO2+H2O

2PbO2+2H2SO42PbSO4+2H2O+O2

(7) Tl2O3 = Basic
Being basic, it reacts with acids to form salts. It reacts with HCl to form thallium chloride.

Tl2O3+6HCl2TlCl3+3H2O


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