The correct option is C Azotobacter
The atmospheric nitrogen is not available to plants. There are some nitrogen fixing bacteria which converts atmospheric nitrogen into ammonia which is readily available to plants. Azotobacter are free-living nitrogen fixing bacteria. Anabaena is a free-living nitrogen fixing bacteria. However, it also forms symbiotic association with plants like mosquito fern. Hence, they are symbiotic bacteria as well.
Thus, the correct answer is 'Azotobacter.'