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Question

A complex cation is formed by Pt(in some oxidation state) with ligands (in proper number so that coordination number of Pt becomes six).


Which of the following can be its correct IUPAC name :

A
Diammineethylenediaminedithiocyanato-S-platinum(II)
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B
Diammineethylenediaminedithiocyanato-S-platinate(IV) ion
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C
Diammineethylenediaminedithiocyanato-S-platinum(IV) ion
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D
Diamminebis (ethylenediamine) dithiocyanato-S-platinum(IV) ion
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Solution

The correct option is C Diammineethylenediaminedithiocyanato-S-platinum(IV) ion
Option (C) is correct.
(A) : [Pt(en)(SCN)2(NH3)2]0; it is not ion.
(B) : [Pt(en)(SCN)2(NH3)2]2+; it should not be platinate
(C) : Correct name. [Pt(en)(SCN)2(NH3)2]2+
(D) : [Pt(en)2(SCN)2(NH3)2]2+; its coordination number is 8.

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