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Structural Isomerism

A complex has...

Question

A complex has a composition corresponding to the formula $C o B r_{2} C l \cdot 4 N H_{3}$ . Silver nitrate solution gives ppt. of $A g C l$ (1 mol) but not of $A g B r$ with isomer $[C o (N H_{3})_{4} C l_{3}] B r$ .
If true enter 1, else enter 0.

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Solution

A complex has formula $C o B r_{2} C l .4 N H_{3}$ .
It gives ppt. of $A g C l$ eual to 1 mole but gives no $A g B r$ . This means that Br is present inside while 1 Cl is present outside. Therefore, the complex is $[C o (N H_{3})_{4} C l_{2} B r] C l$ .
Therefore, the correct answer is 0.

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