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Byju's Answer
Standard VII
Chemistry
Impure Substance
A complex is ...
Question
A complex is given as CoCl3.XNH3 it's 0.1m solution in water shows ∆Tf = 0.558K. Assuming 100% ionisation of complex and Co-ordination number of Co is 6. Calculate the formula of the complex.
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Q.
A complex is represented as
C
o
C
l
3
.
x
N
H
3
its 0.1 molal solution in aq. solution shows
Δ
T
f
=
0.558
0
C
.
K
f
for
H
2
O
is
1.86
K
m
o
l
−
1
k
g
. Assuming
100
%
ionisation of complex and coordination no. of
C
o
is six, calculate formula of complex.
Q.
A complex is represented as
C
o
C
l
3
⋅
X
N
H
3
. Its 0.1 molal solution in water shows
Δ
T
f
=
0.558
o
C
.
K
f
of
H
2
O
is 1.86 K/m. Assuming 100% ionisation, the number of
N
H
3
molecules associated with
C
o
is:
Q.
A complex is represented as
CoC
l
3
x
N
H
3
. Its 0.05 molal solution in water shows
Δ
T
f
=
0.279
K
. Assuming 100% ionisation of complex and co-ordination number of Co to be six, the formula of complex will be (Given
K
f
for
H
2
O
is 1.86
K
m
−
1
)
Q.
A 0.001 molal solution of a complex represented as
[
P
t
(
N
H
3
)
4
C
l
4
]
in water had freezing point depression of
0.0053
o
C
. Given,
K
f
for
H
2
O
=
1.86
K
m
o
l
a
l
i
t
y
−
1
. Assuming 100% ionisation of the complex, write the ionisation nature and formula of complex.
Q.
Compound
P
d
C
l
4
.
6
H
2
O
is a hydrated complex. Its 1 molal aqueous solution has a freezing point of
269.28
K
. Assuming 100% ionization of the complex, calculate the molecular formula of the complex.
(
K
f
for water
=
1.86
Kkgmol
−
1
)
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