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Question

A compound, containing only carbon, and hydrogen and oxygen, has a molecular weight of 44. On complete oxidation it is converted into a compound of molecular weight 60. The original compound is:

A
an aldehyde
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B
an acid
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C
an alcohol
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D
an ether
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Solution

The correct option is C an aldehyde
A compound, containing only carbon, and hydrogen and oxygen, has a molecular weight of 44.
On complete oxidation, it is converted into a compound of molecular weight 60.
The difference in molecular weight is 6044=1660−44=16. It corresponds to one oxygen atom.
The complete oxidation product is a carboxylic acid. One oxygen atom less will be an aldehdye.
The original compound is an aldehyde.

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