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Question

A compound contains carbon 14.4 %, hydrogen 1.2 % and chlorine 84.5 %. The relative molecular mass of this compound is 168, its molecular formula is:[C=12,H=1,Cl=35.5]

A
C2H2Cl3
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B
C2H4Cl4
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C
CH2Cl4
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D
C2H2Cl4
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Solution

The correct option is D C2H2Cl4
Element % composition Atomic weight Relative No. of atoms Simplest ratio
Carbon 14.4 12 14.4/12 = 1.2 1.2/1.2 = 1
Hydrogen 1.2 1 1.2/1 = 1.2 1.2/1.2 = 1
Chlorine 84.5 35.5 84.5/35.5 = 2.38 2.38/1.2 = 2
Hence, empirical formula is CHCl2.
n = Molecular mass/Empirical formula mass
= 168/(12 + 1 + 70)
= 168/83
= 2.
Therefore, molecular formula =(CHCl2)×2=C2H2Cl4.

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