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Question

A compound has O = 61. 32 % S = 11.15 % H = 4.88 % and Zn = 22.65 % The relative molecular mass fo the compound is 287 a.m.u. Find hte molecular formula of the compound assuming that all the hydrogen is present as water of crystallisation.

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Solution

Ans:

Zn S H O
22.65 11.15
4.88
61.32
Step-1(Divide each element percentage with its atomic mass) 22.6565=0.34 11.6532=0.36 4.881=4.88 61.3216=3.83
Step-2 (divide all the obtained values with lowest value & make it nearest round figure value) 0.340.34=1 0.360.34=1 4.880.34=14.35=14 3.830.34=11.26=11
Zn1 S1 7H2(Since all hydrogens are in the form water of crystallization) 7O (Since all hydrogens are in the form water of crystallization. So it requires 7 Oxygen atoms)
&
O4

So, the molecular formula of the compound is ZnSO4.7H2O
Its molecular weight is 65+32+64+(7×18)=161+126=287


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