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Question

A compound has the following percentage composition by mass: carbon 14.4%,hydrogen 1.2% and chlorine 84.5%. Determine the empirical formula of this compound. [H = 1;C=12;Cl = 35.5]


A

CHCl2

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B

CHCl

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C

CHCl4

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D

CH3Cl

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Solution

The correct option is A

CHCl2


Element% compositionAt.Wt,Atomic ratioSimplest atomic ratioCarbon14.41214.412=1.21.21.2=1Hydrogen1.211.21=1.21.21.2=1Chlorine84.535.584.535.5=2.42.41.2=2

Hence, the empirical formula of the compound is CHCl2.


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