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Question

A compound has the following percentage composition by mass-

Carbon-14.4%

Hydrogen-1.2%

Chlorine-85.5%

The relative molecular mass of this compound is 168.50 what ia is molecular formula?

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Solution

Element Percentage composition Atomic weight Relative No. of atoms Simplest ratio
Carbon 14.4 12 14.4/12 = 1.2 1.2/1.2 = 1
Hydrogen 1.2 1 1.2/1 = 1.2 1.2/1.2 = 1
Chlorine 84.5 35.5 84.5/35.5 = 2.38 2.38/1.2 = 2

Hence empirical formula is CHCl2.
n = Molecular mass/Empirical formula mass
= 168/(12 + 1 + 70)
= 168/83
= 2.
Therefore, molecular formula = (CHCl2)2 = C2H2Cl4.


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