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Question

A compound is soluble in water. If ammonia is added to aqueous solution of the compound, a brown precipitate appears which is soluble in dil.HCl. The compound has :

A
Aluminium
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B
Zinc
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C
Iron
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D
Cadmium
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Solution

The correct option is C Iron
The compound is FeCl3 which is soluble in water and forms brown precipitate of Fe(OH)3

FeCl3(aq)+3NH4OH(aq)Fe(OH)3+3NH4Cl

The brown precipitate again converts into FeCl3 on addition of dil HCl which again get solubilized.

Fe(OH)3+3HClFeCl3+H2O

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