A compound X consists of 4.8% carbon and 95.2% bromine by mass.If the vapour density of the compound is 252.What is the molecular formula of the compound?
C2Br6
Element% compositionAtomic WeightAtomic ratioSimplest At. ratioC4.8 %124.812=0.40.40.4=1Br95.2 %8095.280=1.191.190.4=3
Therefore, the empirical formula of the compound is CBr3.
Empirical formula mass = 12 + 80 × 3 = 252
Molecular mass = 2 × V.D. = 2 × 252 = 504
n = Molecular massEmpirical formula mass=504252= 2
Molecular formula = (CBr3)n = (CBr3)2 = C2Br6.