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Question

A compound X consists of 4.8% carbon and 95.2% bromine by mass.If the vapour density of the compound is 252.What is the molecular formula of the compound?


A

C2Br5

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B

C4Br2

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C

C2Br6

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D

C6Br2

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Solution

The correct option is C

C2Br6


Element% compositionAtomic WeightAtomic ratioSimplest At. ratioC4.8 %124.812=0.40.40.4=1Br95.2 %8095.280=1.191.190.4=3

Therefore, the empirical formula of the compound is CBr3.

Empirical formula mass = 12 + 80 × 3 = 252

Molecular mass = 2 × V.D. = 2 × 252 = 504

n = Molecular massEmpirical formula mass=504252= 2

Molecular formula = (CBr3)n = (CBr3)2 = C2Br6.


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