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Question

A compound (X) imports a golden yellow flame and shows the following reactions:
(i) Zinc powder when boiled with a concentrated aqueous solution of (X) dissolves and hydrogen is evolved.

(ii) When an aqueous solution of (X) is added to an aqueous solution of stannous chloride, a white precipitate is obtained first which dissolves in excess of a solution of (X).
The molecular weight of (X) is:

A
40
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B
58.5
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C
85
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D
35
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Solution

The correct option is A 40
The compound (X) is NaOH.
Compound (X) imports a golden yellow flame and shows the following reactions:
(i) Zinc powder when boiled with a concentrated aqueous solution of (X) dissolves and hydrogen is evolved
Zn+NaOHNa2ZnO2+H2
(ii) When an aqueous solution of (X) is added to an aqueous solution of stannous chloride, a white precipitate is obtained first which dissolves in excess of solution of (X) .The molecular weight of X is 40 g/mol.
2NaOH+SnCl2Sn(OH)2whiteppt.+2NaCl
Sn(OH)2+2NaOHNa2SnO2+2H2O

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