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Question

A compound X is obtained by the reaction of alkaline KMnO3 with another compound Y followed by acidification. Compound X also reacts with compound Y in presence of few drops of H2SO4 to form a sweet smelling compound Z. The compound X, Y and Z are respectively.

A
Ethanol, Ethene, Ethanoic acid
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B
Ethanoic acid, Ethanol, Ethylethanoate
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C
Ethanoic Acid, Ethanal, Ethene
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D
Ethanol, Ethanoic Acid, Sodium Ethanoate
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Solution

The correct option is B Ethanoic acid, Ethanol, Ethylethanoate
Ethanoic acid is obtained by the reaction of alkaline KMnO44 with ethanol followed by acidification.

CH3CH2OHi. alkaline KMnO4−−−−−−−−−−ii. acidificationCH3COOH

Ethanoic acid also reacts with ethanol in presence of few drops of H2SO4 to form a sweet smelling ethyl ethanoate.

CH3COOH+CH3CH2OHH2SO4−−−CH3COOCH2CH3

The compound X, Y and Z are ethanoic acid, ethanol, ethylethanoate respectively.

Hence, option (B) is the correct answer.

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