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Question

A compound 'X' undergoes reaction with LiAlH4 to yield another compound 'Y'. When vapours of 'Y' are passed over freshly reduced copper at 300oC, 'X' is formed. The compound 'Y' is

A
CH3COCH3
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B
CH3CHO
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C
CH3CH2OH
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D
CH3OCH3
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Solution

The correct option is C CH3CH2OH
The reduction of acetaldehyde (compound X) with lithium aluminum hydride gives ethanol (compound Y).

Ethanol (compound Y) on oxidation over freshly reduced copper gives back acetaldehyde (compound X).

CH3CHOXLiAlH4(reduction)−−−−−−−−−−−CH3CH2OHY

CH3CH2OHYCu,300oC(oxidation)−−−−−−−−−−−−CH3CHOX

Option C is correct.

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