Synthesis of Aldehydes or Ketones from Hydrocarbons
A compound 'X...
Question
A compound 'X' undergoes reaction with LiAlH4 to yield another compound 'Y'. When vapours of 'Y' are passed over freshly reduced copper at 300oC, 'X' is formed. The compound 'Y' is
A
CH3COCH3
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B
CH3CHO
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C
CH3CH2OH
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D
CH3OCH3
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Solution
The correct option is CCH3CH2OH The reduction of acetaldehyde (compound X) with lithium aluminum hydride gives ethanol (compound Y).
Ethanol (compound Y) on oxidation over freshly reduced copper gives back acetaldehyde (compound X).