A container of 1.0L capacity filled with 1.0 mole of ideal gas is connected to an evacuated vessel of 9.0L. Calculate change in entropy :(R=1.987cal.)
A
0.188calK−1mol−1
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B
0.4576calK−1mol−1
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C
4.576calK−1mol−1
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D
4.366calK−1mol−1
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Solution
The correct option is C4.576calK−1mol−1 Change in entropy =nRlnV2V1 =2.303×1×1.987log101 =2.303×1×1.987 =2.303×1.987 Change in entropy =4.576calK−1mol−1