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Question

A container with rigid walls is covered with perfectly insulating material. The container is divided into two parts by a partition. One part contains a gas while the other is fully evacuated (vacuum). The partition is suddenly removed. The gas rushes to fill the entire volume and comes to equilibrium after a little time. If the gas is not ideal. Choose the correct option:

A
The initial internal energy of the gas equals its final internal energy.
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B
The initial temperature of the gas equals its final temperature.
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C
The initial pressure of the gas equals its final pressure.
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D
The initial entropy of the gas equals its final entropy.
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Solution

The correct option is B The initial internal energy of the gas equals its final internal energy.
Since the wall is expanding against the vaccum ΔW=0
Also, as it is insulated, ΔQ=0

Using first law of thermodynamics,
ΔQ=ΔU+ΔW
ΔU=0

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