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Standard XII

Chemistry

Coordination Complexes

A coordinatio...

Question

A coordination compound X gives pale yellow color with AgNO3 solution while its isomers Y gives white precipitate with BaCl2. Two compounds are isomers of CORSON•5NH3. WHAT COULD BE THE POSSIBLE FORMULA OF 'X' AND 'Y'?

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Q. An octahedral complex with molecular composition

M .5 N H_{3} . C l . S O_{4}

has two isomers,

A

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B

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A

gives a white precipitate with

A g N O_{3}

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B

gives white precipitate with

B a C l_{2}

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Q. The octahedral complex

C o S O_{4} C l_{5} N H_{3}

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X

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A g N O_{3}

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B a C l_{2}

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B a C l_{2}

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Isomers

X

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Q. The octahedral complex

C o S O_{4} C l .5 N H_{3}

exists in two isomeric forms X and Y. Isomer X reacts with

A g N O_{3}

to give a white precipitate, but does not react with

B a C l_{2}

. Isomer Y gives white precipitate with

B a C l_{2}

but does not react with

A g N O_{3}

. Isomer X and Y are

$C o S O_{4} C l .5 N H_{3}$ exists in two isomeric forms 'A and 'B'. Isomer 'A' reacts with $A g N O_{3}$ to give white precipitate, but does not react with $B a C l_{2} .$ Isomer 'B' gives white precipitate with $B a C l_{2}$ but does not react with $A g N O_{3} .$ Answer the following questions.
(a) Identify \A' and 'B' and white their structural formulae
(b) Name the type of isomerism involved.
(c) Give the IUPAC name of 'A' and 'B'.