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Question

A crystal of formula AB3 has A ions at the cube corners and B ions at the edge centres. The coordination numbers of A and B, respectively, are x and y, then the sum of x and y is:

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Solution

Each A atom present at the centre is surrounded by 6 B atoms present at the edges it is connected to (2 in the plane, 2 above the plane and 2 below the plane). Thus the coordination number of A=6.
Each B atom present at edge centre is surrounded by two A atoms at the corners.
x=6
y=2
x+y=8

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