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Question

A crystalline hydrated salt on being rendered anhydrous loses 45.6% of its weight.
The percentage composition of the anhydrous salt is:
Al=10.5%, K=15.1%, S=24.8% and oxygen =49.6%
[Molar mass of Al=27,K=39,S=32].

What is the empirical formula of the salt?

A
K2AlS2O7
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B
K2Al2S2O7
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C
KAlS2O8
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D
K3AlS2O12
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Solution

The correct option is C KAlS2O8
Element%%massAtomic massSimplest ratioAl10.510.527=0.3881K15.115.139=0.3871S24.824.832=0.7752O49.649.616=3.18

Empirical formula = KAlS2O8

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