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Question

A+CS2+HgCl2 gives C2H5−N=C=S. Thus compound A is:

A
C2H5NH2
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B
C2H5NHC2H5
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C
CH3CH=NOH
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D
CH3CH2NO2
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Solution

The correct option is A C2H5NH2
The compound A is ethyl amine. It reacts with carbon disulphide in presence of mercury (II) chloride to form ethyl isothiocyanate.
This reaction is Hofmann mustard oil reaction and is given by primary amines only. Thus it is test for primary amines. Isothiocyanates have pungent smell similar to mustard oil.

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