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Question

A cylinder containing H2O(l) and N2(g) at 25oC recorded a pressure of 500 mbar. The volume of cylinder is reduced to half by forcing the piston downward at the same temperature, the new pressure reading would be (aqueous tension = 23 mbar):

A
977 mbar
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B
1000 mbar
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C
1100 mbar
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D
1023 mbar
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Solution

The correct option is D 977 mbar
PN2=50023=477 mbar.

As the volume of the cylinder is reduced to half, the pressure is doubled.

PN2 after compression 2×477=954 mbar.

Total pressure =954+23=977 mbar.

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