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Question

A cylinder of ideal gas is closed by an 8 kg movable piston of area 60cm2. The atmospheric pressure is 100 kPa. When the gas is heated from 30C to 100C the piston rises 20 cm. The piston is then fastened in the place and the gas is cooled back to 30C. If Q1 is the gas during heating and Q2is the heat lost during cooling, then the difference is (130+x). Find the value of x.

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Solution

Total pressure, P=105+8×9.860×104=1.13×105Nm2

ΔV=0.2×60×104m3
ΔQ1=ΔU1+ΔW1=ΔU1+pΔV=ΔU1+136J
ΔU1=nC(100oC30oC)

ΔQ2=ΔW2+ΔU2=0+nC(30oC100oC)

ΔQ1ΔQ2=136J

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