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Question

A cylindrical tube of length 0.2 m and radius R with sugar solution of concentration 'C' produce a rotation of θ in the plane of vibration of a plane polarized light. The same sugar solution is transferred to another tube of length 0.3 m of same radius. The remaining gap is filled by distilled water. Now the optical rotation produced is.

A
θ
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B
2θ3
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C
3θ2
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D
9θ4
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Solution

The correct option is C θ
In first case, θ=Sl1C1
In second case, θ =Sl2C2
l1=0.2m and l2=0.3m
The solution in the first tube is passed to another tube of 0 m length, so if volume of the first tube is v1 and second tube is v2 and if radius of both tubes are r, then
v2=0.3×πr2=(0.2+0.1)×πr2=3v12
Using proportional sets to calculate concentrations of solution.
C1v1=C2v2
C2=2C13
Hence, θ =Sl2C2=S×0.3×2C13=S×0.2×C1=θ

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