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Question

(a) Define 'formula unit' of an ionic compound. What is the formula unit of
(i) Sodium chloride, and (ii) Magnesium chloride ?
(b) Calculate the formula masses of the following compounds :
(i) Calcium chloride (ii) Sodium carbonate
(Given : Atomic masses : Ca = 40 u; Cl = 35.5 u; Na = 23 u; C = 12 u; O = 16 u)

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Solution

(a). The simplest combination of ions that produces an electrically neutral unit, is called ‘formula unit’ of the ionic compound.
Formula unit of sodium chloride – NaCl
Formula unit of magnesium chloride – MgCl2
(b).
(i). Formula Mass of Calcium chloride (CaCl2) = 1xCa + 2xCl = (40+71) u = 111 u
(ii). Formula Mass of Sodium carbonate (Na2CO3) = 2xNa + 1xC + 3xO= (2×23 + 1×12 + 3×16) u = 106 u

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