(a) The Law of constant proportion states that a chemical compound always contains exactly the same proportion of elements by mass.
For example, pure water obtained from different sources such as River, well, springs always contains hydrogen and oxygen together in the ratio of 1:8 by mass.
(b) First case:
Copper taken = 1.03 g
Copper oxide formed = 1.288 g
Oxygen present = Mass of copper oxide - Mass of copper
= 1.288 - 1.03 = 0.258 g
Hence the ratio of the mass of copper and oxygen in the first case will be:
Mass of copper: Mass of oxygen
= 1.03 : 0.258
= 3.99 : 1
= 4 : 1
Second case:
Copper oxide taken = 3.672 g
Copper produced = 2.938 g
Oxygen present = Mass of copper oxide - Mass of copper
= 3.672 - 2.938 = 0.734 g
Hence the ratio of the mass of copper and oxygen in the first case will be:
Mass of copper: Mass of oxygen
= 2.938: 0.734 = 4 : 1
From the above calculations we can see that the ratio (or proportion) of copper and oxygen elements in the two samples of copper oxide compound is the same 4:1. So, the given figures verify the law of constant proportions.