The correct option is D 13
There are only three determinants of second order with negative value, ∣∣∣0110∣∣∣,∣∣∣0111∣∣∣,∣∣∣1110∣∣∣
Number of possible determinants with elements 0 and 1 are 24=16
therefore, number of determinants with non-negative values is 13.