The correct option is C 13
There are only three determinants of second order with negative values, viz.
∣∣∣0110∣∣∣,∣∣∣0111∣∣∣,∣∣∣1110∣∣∣
The number of possible determinants with elements 0 and 1 is 24=16. Therefore number of determinants with non-negative values is 13.