A diatomic ideal gas is heated at constant volume until the pressure is doubled and again heated at constant pressure until the volume is doubled. The average molar heat capacity for the whole process is
A
13R6
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B
19R6
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C
23R6
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D
17R6
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Solution
The correct option is B19R6 For the isochoric process we have P1T1=P2T2 Thus we get T2=2T1
For isobaric process V2T2=V3T3 Thus we get T3=2T2=4T1 Thus for the entire process we have ΔT=4T1−T1=3T1
For the isochoric process we have heat absorbed as nCvΔT=n52R(2T1−T1) and for isobaric process we have nCpΔT=n(1+52)R(4T1−2T1) Thus we get nCΔT=n(52R)T1+n(72R)2T1 Solving we get C as 196R