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Question

A diatomic ideal gas is heated at constant volume until the pressure is doubled and again heated at constant pressure until the volume is doubled. The average molar heat capacity for the whole process is

A
13R6
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B
19R6
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C
23R6
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D
17R6
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Solution

The correct option is B 19R6
For the isochoric process we have
P1T1=P2T2
Thus we get T2=2T1

For isobaric process
V2T2=V3T3
Thus we get
T3=2T2=4T1
Thus for the entire process we have ΔT=4T1T1=3T1

For the isochoric process we have heat absorbed as nCvΔT=n52R(2T1T1) and for isobaric process we have nCpΔT=n(1+52)R(4T12T1)
Thus we get
nCΔT=n(52R)T1+n(72R)2T1
Solving we get C as 196R

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