A flask containing 0.5 atm pressure of A2(g), some solid AB added into flask which undergoes dissociation according to 2AB(s)⇌A2(g)+B2(g)kp=0.06atm2. The total pressure (in atm) at equilibrium is:
A
0.7
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B
0.6
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C
0.1
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D
none of these
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Solution
The correct option is A 0.7 Totalpressure=2x+0.5KP=(0.5+x)(x)x2+0.5x=0.06x2+0.5x−0.06=0x=0.1and−0.6neglectedTotalpressure=2×0.1+0.5⇒0.70