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Question

A flask containing air at 107 oC and 722 mm of Hg is cooled to 100 K and 760 mm of Hg. If density of the initial condition is 1 g/cm3, then what is the final density in (g/cm3)?

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Solution

Given,
Initial pressure (Pi)=722 mm Final pressure (Pf)=760 mm
Initial temperature (Ti)=(107+273) K=380 K Final temperature (Tf)=100 K
Initial density (di)=1 g /cm3Final density (df)=?
We know, PM=dRT
Where, M=Molar mass
Since M is same here, thus we can write

diTiRPi=dfTfRPf
df=(pfpi)(TiTf)di

=(760722)(380100)×1 g/cm3
=4 g/cm3

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